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Daniel L Akins

Chemistry

Analysis of Structure & Interfaces


Email:
Work: (212) 650-6953

Biography:

Dr. Akins has been a Professor of Chemistry at The City College of New York since 1981, and director of the CUNY-Center for Analysis of Structure and Interfaces since 1988. He holds a doctorate in physical chemistry from the University of California at Berkeley, received in 1968. His mentor at Berkeley was Dr. C. Bradley Moore. From 1968 to 1969, Dr. Akins was a post doctoral associate at the Institute of Molecular Biophysics at The Florida State University (FSU), under the guidance of Dr. Michael Kasha, director. From 1969 to 1970 he served as a visiting assistant professor in the Chemistry Department at FSU. In 1970, Dr. Akins joined the faculty of the Chemistry Department of the University of South Florida, in Tampa, where he rose through the ranks from assistant to associate professor of physical chemistry. In 1977, Dr. Akins took the reins as visiting program director of the physical chemistry subsection of the Dynamics Program at the National Science Foundation. After directing the Dynamics Program for two years, in 1979 Dr. Akins assumed a position as a senior scientist at the Polaroid Corporation, until 1981. Dr. Akins has been published in numerous professional journals. He has extensively lectured at conferences and universities, both national and international. Dr. Akins is a member of several professional organizations, including the American Chemical Society and the Society for Applied Spectroscopy. His principal research focus involves quantum properties of molecular nanostructures and the exploitation of such properties for formulating new nanomaterials with uses in molecular photonic devices (MPDs) and/or chemical sensors. Small groupings of molecules (principally, in our case, so-called molecular aggregates) serve as the active agents. For MPDs the same types of photonic/optoelectronic applications as systems derived from epitaxially prepared inorganic semiconductor superlattices or conjugated organic polymers are anticipated. For chemical sensor applications, the aim is to form robust and highly manipulable new nanomaterials with unique spectral properties for analyses purposes.

Research conducted, more generally, involves: (1) syntheses of semiconductor and magnetic oxide nanoparticles and nanorods within mesoporous aluminosilicates and silicates; (2) fabrication of carbon nanotubes within various matrices; (3) spectroscopic and dynamical investigations of spontaneous and nonlinear laser Raman scattering by monomeric and aggregated molecules on metallic, semiconductor, vesicles surfaces and encapsulated within mesoporous materials; (4) excited state dynamics and determination of photophysical parameters for cyanine dyes and donor-acceptor systems that involve electron-transfer reactions; (5) Raman investigations of porphyrins in solution or adsorbed onto surfaces; (6) spectroscopic studies of biological tissues and herbs; and (7) quantum chemical calculations of porphyrins and dye molecules.

Ten Most Recent Publications:

"Enhanced Dehydrogenation of LiBH4 Catalyzed by Carbon-Supported Pt Nanoparticles," Juan Xu, Xuebin Yu, Zhilin Li, Daniel L. Akins and Hui Yang. Submitted to J. Am. Chem. Soc., July 2008.

"Synthesis and Electrochemical Properties of Singlewalled Carbon Nanotube–Gold Nanoparticle Composites," Huijun Jiang, Yu Zhao, HuiYang and Daniel L. Akins.  Submitted to J. Phys. Chem. C, Feb. 2008.

"Methanol Oxidation on Carbon-Supported Pt-Ru-Ni Ternary Nanoparticle Electrocatalysts," Juanying Liua, Jianyu Cao, Chong Du, Xigui Zhang, Hui Yang and Daniel L. Akins, Submitted to J. Electrochem. Soc., 2008.  (In revision).

"A Biosensing Platform Based on Horseradish Peroxidase Immobilized onto Chitosan Wrapped Single-Walled Carbon Nanotubes," Huijun Jiang, Chong Du, Zhiqing Zou, Xiaowei Li, Daniel L. Akins and Hui Yang.  Accepted in J. of Solid State Electrochemistry, May 2008.

"Direct Electrochemistry and Electrocatalysis of Catalase Immobilized on a SWNT Nanocomposite-Film," Huijun Jiang, HuiYang and Daniel L. Akins.  Article in press, J. Electroanal. Chem. (2008), doi:10.1016/j.jelechem.2008.07.024.

"Coumarin Dye as a Fluorescence Sensor for Methanol Vapor," N. Stevens and D. L. Akins, International Journal of High Speed Electronics and Sensors, World Scientific, 18:1, 195-203 (2008).

"Two Color RNA Intercalating Probe for Cell Imaging Applications," Nathan Stevens, Naphtali O’Connor, Harshad Vishwasrao, Diana Samaroo, Eric R. Kandel, Daniel L. Akins, Charles M. Drain, and Nicholas J. Turro, J. Am. Chem. Soc., 130(23), 7182–7183 (2008).

"AOT Dispersed Single-Walled Carbon Nanotubes for Transistor Device Application," Shiunchin C. Wang, Hui Yang, Sarbajit Banerjee, Irving P. Herman and Daniel L. Akins, Materials Lett., 62, 843-845 (2008), doi:10.1016/j.

"Carbon-Supported Pd-Co Bimetallic Nanoparticles as Electrocatalysts for the Oxygen Reduction Reaction," Wenming Wang, Dan Zheng, Chong Du, Zhiqing Zou, Xigui Zhang, Baojia Xia, Hui Yang and Daniel L. Akins, J. Power Sources, 167, 243-249 (2007).

"Nonlinear Optical Switching Properties of Dye-Doped Inorganic/Organic Nanocomposite Films," N. Stevens and D. L. Akins, ACS Volume Based on Self-Organization of Photonic Nanomaterials, 2007.

 

Email: Dr. Daniel L. Akins

Professor of Chemistry

Director of Center for Analysis of Structures and Interfaces

The Department of Chemistry at The City College

and Ph.D. Program in Chemistry at Graduate Center

of The City University of New York

 
 

Departments:

Chemistry: